Date of Award

12-2009

Level of Access

Campus-Only Thesis

Degree Name

Master of Science (MS)

Department

Earth Sciences

Advisor

Stephen A. Norton

Second Committee Member

Peter O. Koons

Third Committee Member

Ivan J. Fernandez

Additional Committee Members

Brenda L. Hall

Abstract

Sargent Mountain Pond, Maine, USA (SMP) was deglaciated ca. 16,600 Cal Yr BP, forming one of Maine's first lakes following Wisconsinan glaciation. The lake sediment provides one of the region's longest continuous records of post-glacial terrestrial development. Early chemical weathering of apatite (Cas(PO4)3(F,Cl,OH)) from the granitic till caused elevated pH (ca. 6.5 - 7.5) and high concentrations of dissolved calcium (Ca) and phosphorus (P) in the catchment runoff and lake water, relative to present-day conditions. High pH and low soil dissolved organic carbon (DOC) concentrations kept aluminum (Al) and iron (Fe) relatively insoluble and immobile in the catchment, permitting the P released from early apatite weathering to be biologically available. Catchment vegetation developed at SMP ca. 12,700 Cal Yr BP, producing organic acidity (in the form of DOC) that mobilized Al and Fe within the developing catchment soil, and transported them to the lake. The Al and Fe precipitated as oxyhydroxides in the catchment soil and lake sediment, adsorbing dissolved P, thus reducing P bioavailability. The Younger Dryas (ca. 12,200 - 11,500 Cal Yr BP) briefly interrupted the DOC-Al-Fe P-sequestration system. Decreased Al and P sedimentation suggest that the SMP catchment underwent a significant decrease in DOC production, due to decreased temperature, and the lake likely reverted to higher pH and higher bioavailable P. Upon climatic amelioration, ca. 11,500 - 11,000 Cal Yr BP, the SMP system again became dominated by Al hydroxide sedimentation and P adsorption. As apatite became depleted from the active weathering zone of the catchment, the lake progressively acidified (present-day pH ~ 5.0) and the sedimentation of P, nearly all of which was biologically unavailable, decreased. Sediment lead (Pb) isotopes and declining concentration of detrital apatite suggest that apatite became much less abundant in the catchment weathering zone ca. 13,500 Cal Yr BP, relative to its early abundance immediately following deglaciation. Continued P sequestration in the sediment by adsorption (maximum ca. 10,600 Cal Yr BP) indicates that catchment apatite, while much less abundant, was still weathering, after detrital apatite delivery had slowed.

Laboratory chemical weathering experiments on the Cadillac Mountain Granite (the dominant SMP catchment till lithology) provided a mineral-scale test for the catchment-scale interpretations from the sediment core. Accessory mineral weathering, predominantly the weathering of apatite, exerted disproportionately strong control on the overall rock weathering for the first four weeks (of 16 total weeks) of pH 2 mineral acid batch reactor weathering. Later solution chemistry was indicative of a weathering environment that was apatite-depleted and strongly controlled by hornblende and feldspar weathering.

Geochemical modeling of the SMP catchment runoff using ALLOGEN (Boyle, 2007a) successfully predicted the trajectories of base cation concentrations and Pb isotopes in solution, as inferred from the sediment core and measured in the weathering experiments. The modeled runoff became progressively more acidic, dilute, and less radiogenic as catchment minerals (assigned based on Cadillac Mountain Granite petrology) weathered (in the rate order of apatite > hornblende > feldspar > quartz) and organic acidity was introduced to the system according to estimates of the timing of vegetation of the catchment. The model predicted complete apatite depletion from the catchment weathering zone within 2,000 yr. However, the sediment record suggests that apatite was relatively abundant for at least 3,000 yr, and likely for as many as 6,000 yr. Occluded apatite, whose weathering is mediated by the dissolution of host minerals (commonly resistant alumino-silicates) and soil coatings (secondary phases and organic matter), likely persists today; providing low levels of lake water P and a more radiogenic (pre-anthropogenic) Pb isotopic composition in the sediment than would be expected from an apatite-free mineralogy.

These investigations highlighted the dynamic effects of apatite depletion, initiated by large-scale deglaciation and associated climatic warming, on landscape chemical weathering rates and nutrient-P availability. The co-evolution of biology, soils, and biotic and abiotic processes controlling Al and Fe mobility determined the bioavailability of P in the lake ecosystem over the 16,600 yr sediment record. This multiscale approach elucidated mineral-scale processes expressed at the catchment-scale with implications for hemispheric response to deglaciation.

Files over 10MB may be slow to open. For best results, right-click and select "save as..."

Share