Document Type

Article

Publication Title

Journal of Geophysical Research

Publisher

American Geophysical Union

Publication Date

1-20-1994

First Page

1147

Last Page

1156

Issue Number

D1

Volume Number

99

Abstract/ Summary

The concentration of methanesulfonic acid (MSA) was determined in a shallow south central Greenland ice core(20D). This study provides a high-resolution record of the DMS-derived biogenic sulfur in Greenland precipitation over the past 200 years. The mean concentration of MSA is 3.30 ppb(σ = 2.38 ppb,n = 1134). The general trend of MSA is an increase from 3.01 to 4.10 ppb between 1767 and 1900, followed by a steady decrease to 2.34 ppb at the present time. This trend is in marked contrast to that of non-sea-salt sulfate (nss SO42-), which increases dramatically after 1900 due to the input of anthropogenic sulfur. The MSA fraction ((MSA/(MSA+ nss SO42-))* 100) ranges from a mean of 15% in preindustrial ice to less than 5% in recent ice. These MSA fraction suggest that approximately 5 to 40% of the sulfur in recent Greenland ice is of biological origin. It is suggested that there is a significant low-latitude component to the biogenic sulfur in the core and that variations in the MSA fraction reflect changes in the relative strengths of low- and high-latitude inputs. The data shown o evidence for a strong dependence of dimethyl sulfide(DMS) emissions on sea surface temperature during the last century. There is also no indication that the yield of MSA from DMS oxidation has been altered by increased NOx levels over the North Atlantic during this period.

Citation/Publisher Attribution

Whung, P.-Y., E. S. Saltzman, M. J. Spencer, P. A. Mayewski, and N. Gundestrup (1994), Two-hundred-year record of biogenic sulfur in a south Greenland ice core (20D), Journal of Geophysical Research, 99(D1), 1147–1156, doi:10.1029/93JD02732.

Publisher Statement

© Copyright 1994 by the American Geophysical Union

DOI

10.1029/93JD02732

Version

publisher's version of the published document